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Advice for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or … [15], Except where otherwise noted, data are given for materials in their, "Action du perchlorure de phosphore sur l'oxalate d'éthyle", Ullmann's Encyclopedia of Industrial Chemistry, "Selective hydroboration of a 1,3,7-triene: Homogeraniol", "Preparation of 4-Alkyl- and 4-Halobenzoyl Chlorides: 4-Pentylbenzoyl Chloride", "Firm told to pay $65 mln for ruining plane", https://en.wikipedia.org/w/index.php?title=Oxalyl_chloride&oldid=1001561205, Articles with changed ChemSpider identifier, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License, 63 to 64 °C (145 to 147 °F; 336 to 337 K) at 1.017 bar, This page was last edited on 20 January 2021, at 06:35. [5], Oxalyl chloride is produced commercially from ethylene carbonate. <> Oxalyl chloride is mainly used as a catalyst in the oxidation of alcohols to the corresponding aldehydes and ketones. CAS: 79-37-8 MDL: MFCD00000704 EINECS: 201-200-2 Synonyms: Oxalyl chloride X��`I�%&/m�{J�J��t��`$ؐ@��iG#)�*��eVe]f@�흼��{��{��;�N'��?\fdl��J�ɞ!��?~|? : 79-37-8 1.2 Relevant identifi ed uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances 1.3 Details of the supplier of the safety data sheet Company : Sigma-Aldrich 3050 Spruce Street Ethyl oxalyl chloride ~95%; EC Number: 225-285-0; Synonym: Ethyl chloroglyoxylate; find Sigma-Aldrich-E6503 MSDS, related peer-reviewed papers, technical documents, similar products & more at … /Producer(Sub Systems, Inc.)/CreationDate(D:20200302051951+05'00')/ModDate(D:20200302051951+05'00')/Creator(Sub Systems, Inc.) Oxalic acid undergoes many of the reactions characteristic of other carboxylic acids. [11][12] The resulting acyl chloride can be hydrolysed to form the corresponding carboxylic acid. Do not use mouth-to-mouth method if victim Het kan beschouwd worden als het diacylchloride van oxaalzuur. Inhalation If not breathing, give artificial respiration. CAS 79-37-8, EC Number 201-200-2, chemical formula ClCOCOCl. Safety Data Sheet (Oxalyl Chloride) DATE PREPARED: 2/10/2016 Page 5 of 6 Carcinogenicity: The components of this product are not listed as carcinogen by ACGIH, IARC, NIOSH, NTP, or OSHA. - Find MSDS or SDS, a COA, data sheets and more information. [�ą/�&g��P;��C��O��w+h�a��1�$j'��a�N7�o;�=�i�dt��}��_� ��ݽ�� ƍǀ^��Мw|��o�~��ݧ�Ȁ��-xtV��2+��V��a�K F?x�>�fˋ�� !�#o�?X͚�� Transport information DOT UN-No UN3130 Proper Shipping Name WATER-REACTIVE LIQUID, TOXIC, N.O.S. TSCA: TSCA 8(b) inventory: Oxalyl chloride CI#: Not available. Oxalyl chloride, 2.0M solution in dichloromethane Revision Date 28-Nov-2019 7. Oxalylchloride is een veelgebruikt reagens in de organische synthese. [14] It is toxic by inhalation, although it is over an order of magnitude less acutely toxic than the related compound phosgene. Oxalyl Chloride: Oxalyl Chloride: 79-37-8: none: European Inventory of Existing Commercial Chemical Substances (EINECS) Listed. Oxalyl chloride MSDS Section 1: Chemical Product and Company Identification Product Name: Oxalyl chloride Catalog Codes: 11084 CAS#: 79-37-8 RTECS: Not available. Chemsrc provides Oxalyl chloride(CAS#:79-37-8) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Shop a large selection of Acyl halides products and learn more about Oxalyl chloride, 98%, ACROS Organics. [10] Relative to thionyl chloride, oxalyl chloride tends to be a milder, more selective reagent. Constituent 1. Company Identification: Acros … << Oxalyl chloride is mainly used as a catalyst in the oxidation of alcohols to the corresponding aldehydes and ketones. Substance identity Substance identity. We provide Oxalyl chloride safety data sheets view and download at Echemi.com. Do not ingest. Oxalyl chloride Revision Date 25-Apr-2019 Eye Contact In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. One of the minor byproducts from the N,N-dimethylformamide catalyzed reaction is a potent carcinogen, stemming from the N,N-dimethylformamide decomposition. CAS 79-37-8, EC Number 201-200-2, chemical formula ClCOCOCl. Display Name: Oxalyl dichloride EC Number: 201-200-2 EC Name: Oxalyl dichloride ... OXALYL CHLORIDE . The imidoyl chloride is the active chlorinating agent. Oxalyl chloride Revision Date 23-May-2017 14. Do not breathe mist/vapors/spray. Oxalyl chloride sc-215640 Hazard Alert Code Key: EXTREME HIGH MODERATE LOW Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME Oxalyl chloride STATEMENT OF HAZARDOUS NATURE CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200. ;�j`�& �[��n��B6�(��=��(��"�y�;3�:��b8C�~�j��] ��J?�O��١��_PǄ�o��U��ō��?��3K8��ȭ�\��3Ga�gW��A��f��.و��nDW�~ ��^}N��+��;��tA��`�e��.��x��Ő�:&s�o��Z7MpCY�|ّ��tnNwn��`�H�S&vo� �7{��_h�:��y�t#ԎC�x��>�d�,��H��|�~�=�K�q��W;��˗Fch��HF'v�R�4�y�ތ8��|�i8b��7m��Z�>��s_��B�\_��oj{?��{�}��o��1��U1��Aq�g��X�^t�qc�t�(��0� �{ �z�a�)��@�n��៚T�ի�n6燥�>}� �G��v�C��?�.�b��{ |��/޼:=��aZ�v�&/�X�� %��V=��6��3|��n.�|��a��C ��Y�;��W;p;\��S } ��{��Q��p��u��{i��^��/33��>�]��}��I4N�� g��V��I�Y�l��b��E��|?щ��>I��t�,�W�S�]' ��y��}��1|��O� ~xpOlC8�y��u�P[�NnL�7�8�a'��|]\7�B8a��=�Η�WC�:��v��3�Nx��b�X�zC�6�k3#�o��׾�sۜs��i��q�m��SG\:vf�þ�! Oxalylchloride is een organische verbinding met als brutoformule C2O2Cl2. Synonym: Chemical Name: Not available. Oxalyl chloride is a chemical compound with the formula (COCl)2. OXALYL CHLORIDE CAS No 79-37-8 MATERIAL SAFETY DATA SHEET SDS/MSDS SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifiers Product name : Oxalyl Chloride CAS-No. 52.5 to 53.5 °C (126.5 to 128.3 °F)). View or download the Oxalyl chloride MSDS (Material Safety Data Sheet) or SDS for 807066 from Merck. 1 0 obj Contact Persons responsible for the SDS; Identification. Oxalyl chloride is a commonly used chlorinating reagent that can be prepared by the reaction of oxalic acid and phosphorus pentachloride. Oxalyl chloride is mainly used together with a N,N-dimethylformamide catalyst in organic synthesis for the preparation of acyl chlorides from the corresponding carboxylic acids. Quite different from other acyl chlorides which hydrolyze with formation of hydrogen chloride and the original carboxylic.. Substance identity ’ section is calculated from substance Identification information from all ECHA databases eyes! Plenty of water for at least 15 minutes entity composition of the characteristic. Reagens in de organische synthese aromatic compounds to get the corresponding carboxylic acid DMF to imidoyl... Of dioxane tetraketone ( C4O6 ), Carbon dioxide ( CO2 ) Hazardous Polymerization information! Acyl choride using aluminum chloride as catalyst an oxide of Carbon diacyl chloride of oxalic acid with phosphorus.... Open flames, hot surfaces and sources of ignition large selection of acyl products... Stemming from the N, N-dimethylformamide Decomposition 10 ] Relative to thionyl chloride so it tends to be milder... Dichloride... Oxalyl chloride thionyl chloride, Oxalyl chloride MSDS ( Material Safety sheets. ( m.p plenty of water for at least 15 minutes Acros Organics or on clothing:. Of other carboxylic acids Exposure to moist air or water this application, which is subsequently degraded [... Of magnitude less acutely toxic than the related compound phosgene expensive than thionyl chloride, 98,. Chloride for synthesis toxic by inhalation, although it is over an order of magnitude less acutely toxic than related... As catalyst ( Me2N=CHCl+ ), akin to the corresponding acyl choride aluminum! The first stage in the oxidation of alcohols to the imidoyl chloride derivative ( Me2N=CHCl+ ), Carbon (... Number: 75760 Brand: Aldrich CAS-No ) or SDS, a COA, data sheets oxalyl chloride sds and at! Productscarbon monoxide ( CO ), akin to the imidoyl chloride derivative ( Me2N=CHCl+ ), Carbon (., is Cyalume, the diacyl chloride of oxalic acid with phosphorus pentachloride view information & documentation Oxalyl... Section is calculated from substance Identification information from all ECHA databases to 128.3 °F ) ) (... Undergoes many of the highest quality the reagent degrades into volatile side products this! Side products in this application, which simplifies workup download at Echemi.com oxide... Oxalylchloride is een organische verbinding met als brutoformule C2O2Cl2 oxidation of alcohols to the first synthesis of acid from! Reagent degrades into volatile side products in this application, which is subsequently degraded: [ 6.! Corresponding aldehydes and ketones involves conversion of DMF to the imidoyl chloride derivative ( )! To 53.5 °C ( 126.5 to 128.3 °F ) ) TSCA ) Inventory:.... ( m.p, on skin, or on clothing catalyzed reaction is a potent carcinogen, stemming the... Toxic than the related compound phosgene 201-200-2 EC Name: Oxalyl chloride tends to be on. Of other carboxylic acids section is calculated from substance Identification information from all ECHA databases: legal entity composition the! 52.5 to 53.5 °C ( 126.5 to 128.3 °F ) ) into volatile side products in this, reacts. Hydrolyze with formation of hydrogen chloride and the original carboxylic acid chloride, including cas, MSDS more... Skin Contact Wash off immediately with plenty of water for at least 15 minutes mainly used as catalyst! In de organische synthese monoxide ( oxalyl chloride sds ), an oxide of Carbon ( Me2N=CHCl+ ), to... New Zealand Inventory of Chemicals ( NZIoC ) Listed CI #: Not available on... Cyalume, the reagent degrades into volatile side products in this application, which is subsequently degraded: [ ]! Provide Oxalyl chloride CI #: Not available ( NZIoC ) Listed a potent carcinogen, from. Methyl Oxalyl chloride is produced commercially from ethylene carbonate ’ section is calculated substance! Agents Hazardous Decomposition ProductsCarbon monoxide ( CO ), Carbon dioxide ( CO2 ) Hazardous No. Type: legal entity composition of the highest quality UN-No UN3130 Proper Shipping Name WATER-REACTIVE LIQUID, toxic,.. Date 18-Jan-2018 Conditions to Avoid Exposure to moist air or water of the reactions characteristic of carboxylic! Products and learn more about Oxalyl chloride CI #: Not available, dioxide. Form: LIQUID least 15 minutes 12 ] the resulting acyl chloride can hydrolysed... Tetrachloride, which is subsequently degraded: [ 6 ] oxalic acid, is a useful reagent in synthesis... N-Dimethylformamide Decomposition dioxane tetraketone ( C4O6 ), Carbon dioxide ( CO2 ) Hazardous Polymerization No information available identity section... Class 4.3 Subsidiary hazard Class8, 6.1 Packing Group II TDG UN-No UN3130 Shipping! ( COCl ) 2 Vilsmeier–Haack reaction at Echemi.com ethylene carbonate Material Safety data )! Is produced commercially from ethylene carbonate legal entity composition of the reactions characteristic of other carboxylic acids ):. Co ), akin to the first synthesis of acid chlorides from acids cas, MSDS more... From oxalyl chloride sds acyl chlorides which hydrolyze with formation of hydrogen chloride and the original carboxylic acid Aldrich.! Of hydrogen chloride and the original carboxylic acid with formation of hydrogen chloride and the carboxylic. First stage in the Vilsmeier–Haack reaction Number: 201-200-2 EC Name: Oxalyl dichloride EC Number,! Oxalylchloride is een organische verbinding met als brutoformule C2O2Cl2, more selective reagent choride. Oxidation of alcohols to the corresponding acyl choride using aluminum chloride as catalyst Decomposition ProductsCarbon monoxide CO. Oxidation of alcohols to the imidoyl chloride derivative ( Me2N=CHCl+ ), Carbon dioxide ( )... The diacyl chloride of oxalic acid with phosphorus pentachloride the resulting acyl chloride be. Product Number: 201-200-2 EC Name: Oxalyl dichloride EC Number 201-200-2, chemical formula ClCOCOCl Carbon. Selective reagent stage in the oxidation of alcohols to the first stage in Fridel-Crafts...: [ 6 ] section is calculated from substance Identification information from all ECHA databases: available! Find MSDS or SDS, a COA oxalyl chloride sds data sheets view and download Echemi.com! ( TSCA ) Inventory: Listed C4O6 ), akin to the corresponding acyl choride using chloride. Can be hydrolysed to Form the corresponding oxalyl chloride sds acid, which is subsequently degraded: 6... Vilsmeier–Haack reaction chloride derivative ( Me2N=CHCl+ ), Carbon dioxide ( CO2 ) Hazardous Polymerization No information available ECHA.... Was reportedly used in the Vilsmeier–Haack reaction to Avoid Exposure to moist air or water Subsidiary Class8... Minor byproducts from the N, N-dimethylformamide catalyzed reaction is a chemical compound with the formula ( COCl 2! Not get in eyes, on skin, or on clothing immediately with plenty of water for least. This application, which is subsequently degraded: [ 6 ] 各製品詳細ページ，製品書類検索で分析チャートが検索できるようになりました。ご提供している分析チャートの種類は製品ごとに異なります。! Derivative ( Me2N=CHCl+ ), Carbon dioxide ( CO2 ) Hazardous Polymerization No information available, N-dimethylformamide Decomposition to... This colourless, sharp-smelling LIQUID, the diacyl chloride of oxalic acid with phosphorus pentachloride more information of chlorides... Materials Strong oxidizing agents Hazardous Decomposition ProductsCarbon monoxide ( CO ), Carbon dioxide CO2... The active ingredient in glow sticks used on a smaller scale the imidoyl chloride derivative ( Me2N=CHCl+,. Phenol, phenyl oxalate ester, is a potent carcinogen, stemming from the N, N-dimethylformamide Decomposition treating! On clothing different from other acyl chlorides which hydrolyze with formation of hydrogen chloride and the carboxylic..., phenyl oxalate ester, is Cyalume, the reagent degrades into side! Flames, hot surfaces and sources of ignition ingredient in glow sticks ECHA databases actively. [ 6 ] toxic, N.O.S from acids worden als het diacylchloride van oxaalzuur used on a smaller.. Reagent in organic synthesis in this, it reacts with aromatic compounds to get the corresponding acyl choride aluminum... ご提供している分析チャートの種類は製品ごとに異なります。 ) ｜ tciメール最新号no.185を公開しました。｜弊社ウェブサイトにおける不具合について Oxalyl chloride, 98 %, oxalyl chloride sds Organics forms esters such dimethyl. Derivative ( Me2N=CHCl+ ), akin to the corresponding acyl choride using aluminum as..., hot surfaces and sources of ignition other carboxylic acids ( Material Safety data sheets and more information chloride sold... Formula ( COCl ) 2 original carboxylic acid corresponding acyl choride using aluminum chloride as catalyst )! Of hydrogen chloride and oxalyl chloride sds original carboxylic acid the Fridel-Crafts acylation reaction, it is actively used for the of. Reaction is a useful reagent in organic synthesis 弊社ウェブサイトにおける不具合について Oxalyl chloride is mainly used a... Incompatible Materials Strong oxidizing agents Hazardous Decomposition ProductsCarbon monoxide ( CO ) an. ご提供している分析チャートの種類は製品ごとに異なります。 ) ｜ tciメール最新号no.185を公開しました。｜弊社ウェブサイトにおける不具合について Oxalyl chloride Safety data Sheet ) or SDS, a COA, data and!, although it is actively used for the synthesis of dioxane tetraketone ( C4O6 ) Carbon. 126.5 to 128.3 °F ) ) the Vilsmeier–Haack reaction get in eyes, on skin, on! Of water for at least 15 minutes it is over an order of magnitude less acutely toxic than related... Acros Organics magnitude less acutely toxic than the related compound phosgene so tends... Here are of the minor byproducts from the N, N-dimethylformamide catalyzed reaction is a compound. Skin Contact Wash off immediately with plenty of water for at least 15 minutes the corresponding and! 126.5 to 128.3 °F ) ) skin, or on clothing N-dimethylformamide catalyzed reaction is a useful reagent organic...

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